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Effect of methanol on the regioselectivity and reaction rate of 1,3-dipolar cycloaddition of methyldiazoacetate to methyl acrylate and butene-1

✍ Scribed by S.L. Khursan; A.B. Samarkina


Book ID
108286121
Publisher
Elsevier Science
Year
2010
Tongue
English
Weight
403 KB
Volume
959
Category
Article
ISSN
0166-1280

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## Abstract The reaction mechanism and solvent‐dependant regioselectivity of 1,3‐dipolar cycloaddition reactions between azide and acetylene derivatives have been studied using computational methods. The two possible reaction transition states were located. Geometry and NBO analysis found that the