An extended layer of defected SiC has been observed in SiC subjected to heat treatments at 850 and 1050 °C prior to growth of graphene by thermal decomposition. This layer is found to strongly affect the graphene thickness, surface morphology, and Raman spectrum of graphene grown on it. By comparing
Effect of local doping on the electronic properties of epitaxial graphene on SiC
✍ Scribed by Červenka, Jiří ;van der Ruit, Kevin ;Flipse, Kees
- Publisher
- John Wiley and Sons
- Year
- 2010
- Tongue
- English
- Weight
- 549 KB
- Volume
- 207
- Category
- Article
- ISSN
- 0031-8965
No coin nor oath required. For personal study only.
✦ Synopsis
Abstract
Graphene grown on silicon carbide (SiC) is a promising material for high speed electronic devices. However, for possible future applications it is important to understand the electron properties of this material and how it is affected by the interaction with the SiC interface. Here we report an atomically resolved scanning tunneling microscopy and spectroscopy study of local structural and electronic properties of epitaxial graphene. Sharp localized states from the graphene/SiC(0001) interface have been found to strongly influence the electronic properties of the first graphene layer, causing local doping of graphene layer. The disordered high electron density states have originated from the underlying carbon‐rich interface layer whose structure is discussed.
magnified image
Scanning tunneling microscopy images of a first graphene layer on SiC(0001) taken at bias voltage −500 and 500 mV (5 × 5 nm^2^). Red circles and blue crosses indicate that localized states in the filled and empty electron states belonging to the underlying interface layer are located at different positions.
📜 SIMILAR VOLUMES
## Abstract Density functional theory is used to show that charge transfer occurs between chemical dopants in GaAs and adsorbates composed of C~60~ and graphene lying on the (110) surface of GaAs. In the case of C~60~, charge transfer only occurs for n‐type GaAs in agreement with previous experimen
## Abstract AlN doped SiC films were deposited on on‐axis Si‐face 4H‐SiC (0001) substrates by the physical vapor transport (PVT) method. Thick film in the range of 20 μm range was grown and morphology was characterized. Films were grown by physical vapor deposition (PVD) in a vertical geometry in t
The electronic structures of a lithium ion (Li + ) doped-graphene at the ground and low-lying excited states have been investigated by means of density functional theory (DFT) method. A graphene composed of 19 benzene rings was used as a model of graphene, while the edge carbon atom was terminated b