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Effect of Ligands with Extended π-System on the Photophysical Properties of Ru(II) Complexes †

✍ Scribed by Sun, Yujie; El Ojaimi, Maya; Hammitt, Richard; Thummel, Randolph P.; Turro, Claudia

Book ID
126427920
Publisher
American Chemical Society
Year
2010
Tongue
English
Weight
950 KB
Volume
114
Category
Article
ISSN
0022-3654

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The phosphorescence of [ Ru (bhq) (CO )sCI (L) ] (L = PEts, p-toluidine and piperidine ) in glassy rigid solution and in crystals are observed. We have further obtained zero-field splittings by the method of optical detection of magnetic resonance. The location of the spectrum, lifetime, and the zer