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Effect of intramolecular dynamics on state-to-state photochemistry: Fragmentation of the à state of trans-DONO

✍ Scribed by J.H. Shan; R. Vasudev

Publisher
Elsevier Science
Year
1987
Tongue
English
Weight
463 KB
Volume
141
Category
Article
ISSN
0009-2614

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✦ Synopsis

The effect of intramolecular dynamics on state-selected photolysis of trans-DON0 is probed through measurements on the OD fragment ejected by the A state with one and two quanta of energy in the -N=O stretching vibration uZ. The fragment in the latter case is rotationally hotter, more polarized at high rotational energies, and is associated with a higher population non-equilibrium in the n-doublet fine-structure states. These effects are traced back to coupling between the u2 vibration and the in-plane DON angle-bending motion uJ in the parent molecule,

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