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Effect of internal rotation on angular correlation functions of asymmetric tops

✍ Scribed by R. Konrat; H. Sterk

Book ID
103028536
Publisher
Elsevier Science
Year
1989
Tongue
English
Weight
396 KB
Volume
159
Category
Article
ISSN
0009-2614

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✦ Synopsis

The calculation of angular autocorrelation functions and thence lonatudinal relaxation times has been extended to include molecules undergoing anisotropic rotational diffusion with an additional internal motional degree of freedom. Numerical calculations have been performed to study the effects that arc caused by internal mobility. Previous results obtained for axially symmetric molecules, where the axis of rotation is parallel to the molecular symmetry axis, are describedas special cases by our general formula.

πŸ“œ SIMILAR VOLUMES

Angular correlation functions of symmetr
Angular correlation functions of symmetric-top molecules influenced by coriolis coupling
✍ K. MΓΌller; F. KneubΓΌhl πŸ“‚ Article πŸ“… 1973 πŸ› Elsevier Science 🌐 English βš– 162 KB

The influence of rhe Coriolis coupling on the angular autocorreln tion functions (ACF's) of symmetric-top molecules is alculnted startins with the nngulnr ACF's @en by St. Pierre and Stcelc. As on csnmple the theoretical ACF of the ~4 transition of CHCl3 is compared with the experiment. Ln 1969 St.