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Effect of Initial Buffer Composition on pH Changes During Far-From-Equilibrium Freezing of Sodium Phosphate Buffer Solutions

✍ Scribed by Gerardo Gómez; Michael J Pikal; Naír Rodríguez-Hornedo

Book ID
110297169
Publisher
Springer US
Year
2001
Tongue
English
Weight
186 KB
Volume
18
Category
Article
ISSN
0724-8741

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Previous studies have established that the selective precipitation of a less soluble buffer component during freezing can induce a significant pH shift in the freeze concentrate. During freezing of sodium phosphate solutions, crystallization of the disodium salt can produce a pH decrease as great as