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Effect of hydrogen bonding on infrared band intensities of fundamental and overtone transitions: a proposed explanation

✍ Scribed by Surjit Singh; W.A.P. Luck


Book ID
107732908
Publisher
Elsevier Science
Year
1981
Tongue
English
Weight
407 KB
Volume
78
Category
Article
ISSN
0009-2614

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In self-associated hydrogen bonded amines and alcohols the intensity ratio of the "free" and "associated" OH and NH infrared stretching bands is always greater for the overtones than for the fundamentals. It is shown that the Raman bands tend to resemble the infrared overtones in this respect. Both