Effect of high pressure on the radical polymerization of methyl methacrylate, inhibited by p-benzoquinone
β Scribed by V.M. Zhulin; R.I. Baikova; M.D. Pushkinskii
- Book ID
- 118360745
- Publisher
- Elsevier Science
- Year
- 1974
- Weight
- 222 KB
- Volume
- 16
- Category
- Article
- ISSN
- 0032-3950
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## Abstract The radical polymerization of methyl methacrylate has been carried out at 51Β°C. over a pressure range of 1β8000 kg./cm.^2^, and the stereochemistry of the polymer analyzed by NMR spectroscopy. Over the entire pressure range, the stereochemistry of addition is independent of the stereoch
## Abstract Bulk polymerizations of methyl methacrylate (MMA) at 60Β°C initiated with 2,2β²βazoisobutyronitrile are influenced by the presence of an organic Οβdonor such as tetrathiafulvalene (TTF). Upon addition of TTF, the ratio of weightβ to numberβaverage molecular weights __MΜ__~w~/__MΜ__~n~ are