Pressure effect on the rate and equilibr
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Vladimir D. Kiselev; Elena A. Kashaeva; Alexander I. Konovalov
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Article
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1999
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Elsevier Science
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French
β 451 KB
The pressure effect on the forward and backward rate constants and equilibrium constants of the Diels-Alder reaction of 9-chloroanthracene with tetracyanoethylene has been investigated in 1,2-dichloroethane up to 1000 kgcm -2 at 298.15 K. The reaction volume obtained from the pressure effect on equi