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Effect of Diphenylamine on the Synthesis of Carotene

✍ Scribed by SCHNEIDER, GY.; MATKOVICS, B.; ZSOLT, J.; KOVÁCS, Ö.

Book ID: 109607798
Publisher: Nature Publishing Group
Year: 1960
Tongue: English
Weight: 111 KB
Volume: 186
Category: Article
ISSN: 0028-0836
DOI: 10.1038/186235a0

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## Photocyclization of diphenylamine (DPA) in cyclohexane is accelerated by the addition of hydrogen-bonding agents (Q). Laser photolysis studies reveal that Q principally affects the S1 state of DPA. DPA in its S1 state forms a stable hydrogen-bonding complex with Q in which DPA acts as a proton