The ionic liquids n-butylpyridinium tetrafluoroborate [bupy]BF 4 and 1-n-butyl-3-methylimidazolium tetrafluoroborate [bmim]BF 4 have been used as solvents for the Rh(I) catalyzed phenylacetylene polymerization in the presence of triethylamine as co-catalyst, obtaining high yields of poly(phenylacety
โฆ LIBER โฆ
Effect of Diene Ligands in the Rhodium-Catalyzed Polymerization of Phenylacetylene
โ Scribed by Saeed, Irfan; Shiotsuki, Masashi; Masuda, Toshio
- Book ID
- 127221734
- Publisher
- American Chemical Society
- Year
- 2006
- Tongue
- English
- Weight
- 63 KB
- Volume
- 39
- Category
- Article
- ISSN
- 0024-9297
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Some new Rh(1) and Ir(1) complexes of the types [(COD)M(LL)]ClO, and [(COD)MCI], [COD = cyclooctadiene; M = Rh, Ir; LL = 1,l'-bis(dipheny1phosphino)ferrocene (DPPF), 1 -diphenylphosphino-2-(N,N-dimethylamino)methylferrocene (FcNP), 1,6-diferrocenyl-2,5diazahexane (FcNN)] were prepared, and their cat