✦ LIBER ✦

Stereoregular Polymerization of Phenylacetylenes Catalyzed by [Hydridotris(pyrazolyl)borato]rhodium(I) Complexes

✍ Scribed by Katayama, Hiroyuki; Yamamura, Kunihiro; Miyaki, Yoshiharu; Ozawa, Fumiyuki

Book ID: 120325354
Publisher: American Chemical Society
Year: 1997
Tongue: English
Weight: 183 KB
Volume: 16
Category: Article
ISSN: 0276-7333
DOI: 10.1021/om9703090

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

Living polymerization of phenylacetylene

Living polymerization of phenylacetylenes catalyzed by cationic rhodium complexes bearing tetrafluorobenzobarrelene

✍ Shiotsuki, Masashi; Onishi, Naoya; Sanda, Fumio; Masuda, Toshio 📂 Article 📅 2010 🏛 Nature Publishing Group 🌐 English ⚖ 517 KB

Polymerization of phenylacetylene and of

Polymerization of phenylacetylene and of p-tolylacetylene catalyzed by β-dioxygenato rhodium(I) complexes in homogeneous and heterogeneous phase

✍ Piero Mastrorilli; Cosimo Francesco Nobile; Antonino Rizzuti; Gian Paolo Suranna 📂 Article 📅 2002 🏛 Elsevier Science 🌐 English ⚖ 120 KB

Oligomerization and polymerization of al

Oligomerization and polymerization of alkynes catalyzed by rhodium(I) pyrazolate complexes

✍ G.Attilio Ardizzoia; Stefano Brenna; Sergio Cenini; Girolamo LaMonica; Norberto 📂 Article 📅 2003 🏛 Elsevier Science 🌐 English ⚖ 134 KB

Living polymerization of phenylacetylene

Living polymerization of phenylacetylene by rhodium-based ternary catalysts, (diene)Rh(I) complex/vinyllithium/phosphorus ligand. Effects of catalyst components

✍ Yoshihiko Misumi; Keiji Kanki; Michihiro Miyake; Toshio Masuda 📂 Article 📅 2000 🏛 John Wiley and Sons 🌐 English ⚖ 71 KB

Polymerization of arylallenes catalyzed

Polymerization of arylallenes catalyzed by organo-rhodium(I) and -cobalt (I) complexes to give structurally regulated high-mass polymers

✍ J.-C. Choi; K. Osakada; I. Yamaguchi; T. Yamamoto 📂 Article 📅 1997 🏛 John Wiley and Sons 🌐 English ⚖ 143 KB 👁 2 views

## Organorhodium complexes, such as RhH(PPh 3 ) 4 , RhH(CO)(PPh 3 ) 3 , Rh( 3 -C 3 H 4 Ph)(CO)(PPh 3 ) 2 , and RhH(dppe) 2 [dppe = 1,2 -bis(diphenylphosphinoethane)], catalyze polymerization of phenylallene and of 4-methylphenylallene at 60 °C. High-molecular-weight polymers (M n > 4ϫ 10 5 ) are i

Kinetic and mechanistic investigation of

Kinetic and mechanistic investigation of the sequential hydrogenation of phenylacetylene catalyzed by rhodium (I) phosphine complexes of the type [Rh(η2-O2Z)(PR3)2]

✍ U. Möhring; M. Schäfer; F. Kukla; M. Schlaf; H. Werner 📂 Article 📅 1995 🏛 Elsevier Science 🌐 English ⚖ 708 KB

Chelate complexes of the type [ Rh( q2-0,Z) (PR,),] (Z = CCH,, CCF3, CtBu, S( 0) -p-C&I&H,; PR, = PiPr,, PPhiPr,, PPh,iPr) catalyze the hydrogenation of phenylacetylene in toluene solution at 60°C. Selectivities close to 100% are achieved for the hydrogenation of the alkyne to the alkene in the pre