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Effect of dichloromethane on the reaction of carbethoxynitrene with trans-1,2-dimethylcyclohexane

โœ Scribed by Belloli, Robert C.; Whitehead, Mark A.; Wollenberg, Robert H.; LaBahn, Valerie A.


Book ID
125898231
Publisher
American Chemical Society
Year
1974
Tongue
English
Weight
451 KB
Volume
39
Category
Article
ISSN
0022-3263

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โœ H.H. Wasserman; L.S. Keller ๐Ÿ“‚ Article ๐Ÿ“… 1974 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 201 KB

In previous studies on the stereochemistry of benzyne addition to enol ethers and acetates we observed both stereoselective 2+2 cycloaddition and ene reaction. 1 In each series, however, we found that the proportion of ene product relative to cycloaddition was significantly larger with the trans-is