Effect of detergents on the conformation of proteins. II. Optical rotatory dispersion by using ultraviolet light
✍ Scribed by B. Jirgensons
- Book ID
- 118843935
- Publisher
- Elsevier Science
- Year
- 1962
- Tongue
- English
- Weight
- 456 KB
- Volume
- 96
- Category
- Article
- ISSN
- 0003-9861
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Ultraviolet optical rotatory dispersion curves of mucopolysaccharides exhibit particular Cotton effects in the spectral region of the It-x and T-T amide transitions. Two general patterns emerge: (I) enhancement of negative rotation and of the first negative Cotton effect (troughs 217-220 mp) and (2)
## Abstract The effect of salts on the coil‐to‐helix transition of poly‐α‐amino acids was investigated by optical rotatory dispersion and potentiometric titration techniques. Both charge‐dependent and charge‐independent contributions to the free energy were considered. The free energy of formation