Binding of alcohols to the peptide CO-group of poly-L-proline in the I and II conformation. I. Demonstration of the binding by infrared spectroscopy and optical rotatory dispersion

Binding of alcohols to the peptide CO gr

Binding of alcohols to the peptide CO group of poly-L-proline in the I and II conformation. II. Binding constants from infrared measurements in solution

✍ H. Strassmair; J. Engel; S. Knof 📂 Article 📅 1971 🏛 Wiley (John Wiley & Sons) 🌐 English ⚖ 847 KB

## Eiweiss-und Lederforschung, Munich, Germanq synopsis Trifluoroet.hatio1, benxyl alcohol, and n-butanol bind to the peptide and acetyl CO groups of po1y-O-acetyl-Lhydroxyproline in dichloromethane via hydrogen bonds. The binding affinity decreases from trifluoroethanol to n-butanol. For t.he ace