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Effect of conjugation beyond multiple bonds on geometry and acidity

✍ Scribed by Zhixing Chen

Book ID
119116016
Publisher
Elsevier Science
Year
1983
Tongue
English
Weight
641 KB
Volume
105
Category
Article
ISSN
0166-1280

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πŸ“œ SIMILAR VOLUMES

Substituent effect on relative stabiliti
Substituent effect on relative stabilities of the phosphorus and tin multiple bonds
✍ Ya-Hui Hu; Ming-Der Su πŸ“‚ Article πŸ“… 2003 πŸ› Elsevier Science 🌐 English βš– 235 KB

The unimolecular rearrangement of XSnBP (X ΒΌ H, Li, BeH, BH 2 , CH 3 , NH 2 , OH, and F) to Sn@PX is considered using B3LYP and QCISD calculations. The theoretical findings suggest that the doubly bonded Sn@PX molecule is intrinsically more stable than the triply bonded XSnBP species, regardless of