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Effect of Cl substituent in the aromatic tetracycline ring on its reactivity with solvated electrons

✍ Scribed by J. O. Dzięgielewski; P. Głowacki; J. Gorący; D. Orłowska-Dudek; E. Słoma


Book ID
112709224
Publisher
Springer
Year
1984
Tongue
English
Weight
281 KB
Volume
87
Category
Article
ISSN
1588-2780

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✍ Nizar El Guesmi; Taoufik Boubaker 📂 Article 📅 2011 🏛 John Wiley and Sons 🌐 English ⚖ 155 KB

## Abstract A kinetic study is reported for S~N~A~r~ reactions of 2,4,6‐tris(trifluoromethanesulfonyl) anisole 1a with a series of para‐X‐substituted anilines 2a–e in a methanol solution at various temperatures. The substituent effects on free energy (Δ^≠^__G__), enthalpy (Δ^≠^__H__), and entropy (