๐”– Bobbio Scriptorium
โœฆ   LIBER   โœฆ

Effect of chemical diffusivity on the peak shapes in flow injection analysis with sample or reagent injection

โœ Scribed by Jinxin Li; Guojun Liu; Huichang Ma; Takashi Korenaga


Publisher
Elsevier Science
Year
1995
Tongue
English
Weight
590 KB
Volume
310
Category
Article
ISSN
0003-2670

No coin nor oath required. For personal study only.

โœฆ Synopsis


This paper deals with the difference in residence time of the two reagent/sample interface peaks produced in a single channel manifold. This difference in residence time is explained on the basis of a dispersion model, and the relevant factors were studied. It was found that in both sample injection (SI) and reagent injection (RI), in addition to the relative reagent and sample concentrations and injection volumes, the diffusivities of the sample and the reagent will affect the peak shape and detection sensitivity. The sensitivity in peak height measurements and peak area measurements in SI and RI are compared and explained.


๐Ÿ“œ SIMILAR VOLUMES


Effect of sample viscosity on the behavi
โœ Lars Risinger; Gillis Johansson ๐Ÿ“‚ Article ๐Ÿ“… 1992 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 535 KB

VISCOUS samples unll cause pressure changes which affect the transfer of solutes through an on-lme dlalyzer Pressure changes can cause pre-peaks m the recorded slgnal due to membrane movements The flow-rate m the reuxver channel mcreases temporanly as the pressure budds up A pressure dtfferentml of