Effect of cerium(III) and cerium(IV) on chromic acid oxidations. Elimination of the chromium(IV)-alcohol oxidation
โ Scribed by Doyle, Michael.; Swedo, Raymond J.; Rocek, Jan.
- Book ID
- 119966818
- Publisher
- American Chemical Society
- Year
- 1973
- Tongue
- English
- Weight
- 709 KB
- Volume
- 95
- Category
- Article
- ISSN
- 0002-7863
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๐ SIMILAR VOLUMES
## Abstract For Abstract see ChemInform Abstract in Full Text.
Kinetics and mechanism of the cerium(1V) oxidation of Cr(II1) complexes of a series of macrocyclic (or pseudomacrocyclic) ligands with L14l-membered intraligand rinqsizes have now been investigated at I = 1.0 Tvf !LiClO.d Temp. 30ยฐC. The complexes of' the formulation Cr(macrocycle)(X)(H20)'3 ''I-whe
The cerium(IV) oxidation of isobutanol, isoamyl alcohol isopropyl alcohol, and secondary butanol catalysed by chromium(III) was studied in sulphuric and perchloric acid mixture at 30 ยฐC. The reaction was found to proceed with the formation of a chromium(IV) intermediate followed by its complexation