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Effect of bending on the predissociation dynamics of N2O+

✍ Scribed by S. Miret-Artes; G. Elgado-Barrio; O. Atabek; J.A. Beswick

Publisher
Elsevier Science
Year
1983
Tongue
English
Weight
478 KB
Volume
98
Category
Article
ISSN
0009-2614

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✦ Synopsis

In tbik p~prr w introduce a modified version of the infinite-order sudden approGmation (IOSA) for rotational and bend-in_r de?l_r~es of freedomz togetfler with a distorted-wave treatment of stretching vibrations, to study predissociation lifetimes for the A state of NzO . We present a compxbon bet\ een the e.\perimental results by Klapstein and hlaier and several model wlculations M ith different bendin: behavior of the final dissociative potential energy surf&e. It is shown that inclusion of bending dyn,wics modifies considerably the predissociation lifetimes.

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