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Effect of atmosphere composition on the oxidation behavior of MCrAlY coatings

✍ Scribed by P. Song; M. Subanovic; J. Toscano; D. Naumenko; W. J. Quadakkers


Publisher
John Wiley and Sons
Year
2010
Tongue
German
Weight
558 KB
Volume
62
Category
Article
ISSN
0947-5117

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✦ Synopsis


Abstract

In the present work the effect of atmosphere composition on the growth rate and adherence of the alumina scales was studied using free‐standing MCrAlY‐coatings and TBC‐specimens with MCrAlY‐bondcoats. The exposures comprised isothermal and cyclic exposures in laboratory air and Ar‐H~2~‐H~2~O at 1100 °C.

It is shown that minor Zr‐addition to the bondcoat results in enhanced scale growth and internal oxidation. This effect is independent of the atmosphere composition. As a consequence of the rapid oxide formation the times to TBC failure on the Zr‐containing bondcoat in both atmospheres were much shorter compared to those with Zr‐free bondcoat. In the latter case the formation of a thin compact alumina TGO was slower in H~2~/H~2~O than in air resulting in significantly longer TBC‐lifetime in the former atmosphere.


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