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Effect of Aprotic Solvents on Intermolecular Interaction of Cellulose Macromolecule with N-Methylmorpholine N-Oxide Monohydrate

✍ Scribed by N. P. Novoselov; E. S. Sashina; E. V. Don'shina

Book ID
110337358
Publisher
SP MAIK Nauka/Interperiodica
Year
2002
Tongue
English
Weight
33 KB
Volume
75
Category
Article
ISSN
1070-4272

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On the conformation of the cellulose solvent N-methylmorpholine-N-oxide (NMMO) in solution
✍ T. Rosenau; A. Hofinger; A. Potthast; P. Kosma πŸ“‚ Article πŸ“… 2003 πŸ› Elsevier Science 🌐 English βš– 150 KB

The N-oxide group of the cellulose solvent N-methylmorpholine-N-oxide showed a strong preference for the axial position compared with N-methyl as determined by NMR experiments and computational studies. In solvents with negligible solvent -solute interaction, about 95% of the NMMO molecules obtained