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Effect of added Ru3(CO)12 on the indirect hydrogenation of cellulose

✍ Scribed by John D. Cotton; Janelle C. Penrose; Peter R. Wells

Publisher
Elsevier Science
Year
1982
Tongue
English
Weight
230 KB
Volume
61
Category
Article
ISSN
0016-2361

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✦ Synopsis

Addition of small amounts of RIJ~(CO),~ to a mixture of a cellulose substrate, sodium carbonate, carbon monoxide and water significantly enhances the extent of conversion and the H:C ratio in the oil produced in the indirect hydrogenation process at 250-350Β°C; however, the oxygen content of the oil is slightly higher. The possible function of the added Ru,_(CO),~, a known catalyst for the water-gas shift reaction, is discussed.

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Recently there has been growing interest in the interaction of carbonyl clusters with oxidic surfaces. Because of its simple structure and well-known chemical behaviour, Rua(CO)iZ has been studied by several authors [l-4]. Qualitative examination of the IR spectra suggests that, depending on the ci