Effect of acetylation on dimensional stability, mechanical, and dynamic properties of jute board

✍ Scribed by A. K. Rana; B. C. Mitra; A. N. Bannerjee

• Publisher: John Wiley and Sons
• Year: 1999
• Tongue: English
• Weight: 261 KB
• Volume: 72
• Category: Article
• ISSN: 0021-8995
• DOI: 10.1002/(sici)1097-4628(19990516)72:7<935::aid-app9>3.0.co;2-w

✦ Synopsis

Jute slivers were acetylated in pilot scale following a no catalyst-no solvent method at 120°C for 2 h. The weight % gain was found to be 11.37. Different jute boards were pressed under heat and pressure using acetylated jute sliver and urea formaldehyde resin. Neutral salt (NaCl), acid salt (NH 4 Cl), and melamine powder were used separately for curing urea formaldehyde. For comparison purposes, control boards were also prepared using nonacetylated slivers. The boards were tested for water soaking, cyclic water soaking, and cyclic humidity to see the effect of acetylation on dimensional stabilization. This chemical modification was found to improve the dimensional stability to a great extent for NaCl and NH 4 Cl cured boards and to a less extent for a melamine-cured one. Tensile and flexural strengths were tested by Instron before and after the cyclic tests. Retention values were found to be as high as 60% after cyclic water tests for acetylated boards and the same was as low as 24% for control boards. Dynamic parameters, such as storage flexural modulus (EЈ), loss flexural modulus (EЉ), and loss factor or damping efficiency (tan ␦) were determined in a fixed-frequency mode. Dynamic mechanical study revealed that tan ␦ peaks were lowered due to increased bulkiness of the fiber after acetylation and thus restricted mobility. A tiny additional peak was also visible at ϳ90°C beside the main peak at ϳ125°C for boards with modified slivers.