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Effect of A-strain on a diastereoselective synthesis of 6-hydroxy-4a-aryldecahydroisoquinolines; revised structures of N-acyliminium ion-polyene cyclization products

✍ Scribed by Kano, Shinzo; Yokomatsu, Tsutomu; Nemoto, Hajime; Shibuya, Shiroshi


Book ID
127000958
Publisher
American Chemical Society
Year
1986
Tongue
English
Weight
592 KB
Volume
51
Category
Article
ISSN
0022-3263

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## Abstract Azo coupling of 6‐amino‐4‐hydroxy‐2‐naphthalenesulfonic acid **(1)** with 3‐trifluoromethyl‐ and 4‐nitrobenzenediazonium ion in relative highly concentrated aqueous alkaline solutions gave ratios of aminoazo to hydroxyazo compounds which are much higher than expected on the basis of the