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Effect of a phase-transfer catalyst on the chemical modification of poly(vinyl chloride) by substitution with thiocyanate as a nucleophile

✍ Scribed by Tomohito Kameda; Masahiko Ono; Guido Grause; Tadaaki Mizoguchi; Toshiaki Yoshioka


Book ID
113783324
Publisher
Elsevier Science
Year
2009
Tongue
English
Weight
589 KB
Volume
118
Category
Article
ISSN
0254-0584

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Chemical modification of rigid poly(viny
✍ Tomohito Kameda; Yuuzou Fukuda; Guido Grause; Toshiaki Yoshioka πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons 🌐 English βš– 483 KB πŸ‘ 2 views

## Abstract The reaction of rigid poly(vinyl chloride) (PVC) with iodide, hydroxide, azide, and thiocyanate as nucleophiles (Nu) in ethylene glycol (EG) resulted in the substitution of Cl by Nu additional to the elimination of HCl, leading to the dehydrochlorination of the rigid PVC. High substitut