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Chemical modification of flexible and rigid poly(vinyl chloride) by nucleophilic substitution with thiocyanate using a phase-transfer catalyst

✍ Scribed by Tomohito Kameda; Yuuzou Fukuda; Guido Grause; Toshiaki Yoshioka

Book ID: 113783730
Publisher: Elsevier Science
Year: 2010
Tongue: English
Weight: 342 KB
Volume: 124
Category: Article
ISSN: 0254-0584
DOI: 10.1016/j.matchemphys.2010.06.011

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## Abstract The reaction of rigid poly(vinyl chloride) (PVC) with iodide, hydroxide, azide, and thiocyanate as nucleophiles (Nu) in ethylene glycol (EG) resulted in the substitution of Cl by Nu additional to the elimination of HCl, leading to the dehydrochlorination of the rigid PVC. High substitut