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Edge-to-face aromatic interactions in alkenes, nitrones and imines

โœ Scribed by Boyd, Derek R.; Evans, Timothy A.; Jennings, W. Brian; Malone, John F.; O'Sullivan, William; Smith, Allison


Book ID
119954607
Publisher
Royal Society of Chemistry
Year
1996
Tongue
English
Weight
319 KB
Volume
19
Category
Article
ISSN
1359-7345

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Chemical double mutant cycles have been used to measure the magnitude of edge-to-face aromatic interactions in hydrogen-bonded zipper complexes as a function of substituents on both aromatic rings. The interaction energies vary depending on the combination of substituents from +1.0 kJ mol-1 (repulsi