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An Electrochemically Controllable Nanomechanical Molecular System Utilizing Edge-to-Face and Face-to-Face Aromatic Interactions

✍ Scribed by Kim, Heon Gon; Lee, Chi-Wan; Yun, Sunggoo; Hong, Byung Hee; Kim, Young-Ok; Kim, Dongwook; Ihm, Hyejae; Lee, Jung Woo; Lee, Eun Cheol; Tarakeshwar, P.; Park, Su-Moon; Kim, Kwang S.


Book ID
121290314
Publisher
American Chemical Society
Year
2002
Tongue
English
Weight
71 KB
Volume
4
Category
Article
ISSN
1523-7060

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Substituent Effects on Edge-to-Face Arom
✍ Fiona J. Carver; Christopher A. Hunter; David J. Livingstone; James F. McCabe; E πŸ“‚ Article πŸ“… 2002 πŸ› John Wiley and Sons 🌐 English βš– 944 KB

Chemical double mutant cycles have been used to measure the magnitude of edge-to-face aromatic interactions in hydrogen-bonded zipper complexes as a function of substituents on both aromatic rings. The interaction energies vary depending on the combination of substituents from +1.0 kJ mol-1 (repulsi