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Easy Access to Chain-Length-Dependent Termination Rate Coefficients Using RAFT Polymerization

✍ Scribed by Philipp Vana; Thomas P. Davis; Christopher Barner-Kowollik


Publisher
John Wiley and Sons
Year
2002
Tongue
English
Weight
113 KB
Volume
23
Category
Article
ISSN
1022-1336

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## Abstract **Summary:** The RAFT‐CLD‐T methodology is demonstrated to be not only applicable to 1‐substituted monomers such as styrene and acrylates, but also to 1,1‐disubstituted monomers such as MMA. The chain length of the terminating macromolecules is controlled by CPDB in MMA bulk free radica

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The photosensitized polymerization of styrene in bulk was investigated in the temperature range of 25-70Β°C with respect to the average rate coefficient of bimolecular chain termination k t , especially its chain length dependence at low conversions, by means of pulsed laser polymerization (PLP). Thr