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E 2 (CN) 2 (E = S, Se) and Related Compounds

✍ Scribed by Burchell, Colin J.; Kilian, Petr; Slawin, Alexandra M. Z.; Woollins, J. Derek; Tersago, Karla; Van Alsenoy, Christian; Blockhuys, Frank

Book ID: 125910861
Publisher: American Chemical Society
Year: 2006
Tongue: English
Weight: 118 KB
Volume: 45
Category: Article
ISSN: 0020-1669
DOI: 10.1021/ic0515103

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Liganden enthalten, sowie über die Synthese von 3, die Hinweise auf den Mechanismus der Bildung von 1 und 2 liefern könnte. Wir erhielten 1 durch Umsetzen von [{IrCl(cod)} 2 ] mit AgBF 4 und [K([2.2.2]cryptand)] 2 [Se n ] (n 3, 5, 6) in flüssigem Ammoniak und anschlieûende Extraktion des Rückstands