(E)-1-(4-Bromobenzylidene)ferrocene
✍ Scribed by Zhao, Zu-Zhi ;Li, Lin ;Wu, Jie-Ying
- Publisher
- International Union of Crystallography
- Year
- 2006
- Tongue
- English
- Weight
- 76 KB
- Volume
- 62
- Category
- Article
- ISSN
- 1600-5368
No coin nor oath required. For personal study only.
✦ Synopsis
In the title compound, [Fe(C 5 H 5 )(C 13 H 10 Br)], the benzene ring makes a dihedral angle of 14.1 (2) with the substituted cyclopentadienyl ring. The bond distances imply that there is no conjugation between the cyclopentadienyl and benzene rings.
📜 SIMILAR VOLUMES
N-(4-Bromobenzylidene)-2-hydroxyaniline, C 13 H 10 BrNO, exists as a planar molecule in which the hydroxy group is intramolecularly hydrogen bonded to the imino N atom.
Single-crystal X-ray study T = 291 K Mean (C-C) = 0.005 A R factor = 0.051 wR factor = 0.113 Data-to-parameter ratio = 15.4 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.