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Dynamics of eight-membered rings. 1,3-Dioxocane and its gem-dimethyl derivatives

โœ Scribed by Anet, F. A. L.; Degen, P. J.; Krane, J.


Book ID
125980539
Publisher
American Chemical Society
Year
1976
Tongue
English
Weight
832 KB
Volume
98
Category
Article
ISSN
0002-7863

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Dynamics of seven- and eight-membered 1,
โœ Frank A.L. Anet; Ragini Anet; Michael P. Trova; Leo A. Paquette ๐Ÿ“‚ Article ๐Ÿ“… 1989 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 301 KB

The conformations and conformational dynamics of the two title hydrocarbons have been determined by lH 500 MHz NMR and molecular mechanics calculations; barriers for the Cope rearrangements are also reported. The semibullvalene (SBV) molecule (1) has a rigid tricyclic stmcture (C, point group symme