Dynamics of seven- and eight-membered 1,
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Frank A.L. Anet; Ragini Anet; Michael P. Trova; Leo A. Paquette
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Article
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1989
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Elsevier Science
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French
โ 301 KB
The conformations and conformational dynamics of the two title hydrocarbons have been determined by lH 500 MHz NMR and molecular mechanics calculations; barriers for the Cope rearrangements are also reported. The semibullvalene (SBV) molecule (1) has a rigid tricyclic stmcture (C, point group symme