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Dynamics of crown and lariat ether cation complexation assessed by carbon-13 NMR relaxation times

โœ Scribed by Echegoyen, Luis; Kaifer, Angel; Durst, H.; Schultz, Rose Ann; Dishong, Dennis M.; Goli, Deepa M.; Gokel, George W.


Book ID
125482223
Publisher
American Chemical Society
Year
1984
Tongue
English
Weight
545 KB
Volume
106
Category
Article
ISSN
0002-7863

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We r port resolution of individual carbon environments of 18-crown-6 ether and its KNCS complex using I5 C CPMAS nuclear magnetic resonance spectroscopy at low temperature. The importance of torsional angle effects in determining chemical shifts in these solids is discussed.