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Dynamical response and H-bond effects in confined liquid water

✍ Scribed by V. Crupi; S. Magazù; D. Majolino; G. Maisano; P. Migliardo

Publisher
Elsevier Science
Year
1999
Tongue
English
Weight
665 KB
Volume
80
Category
Article
ISSN
0167-7322

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✦ Synopsis

An analysis of Rayleigh wing and Raman scattering data performed in water confined in a nanoporous GelSil matrix, is presented. In the restricted translational region, the results show a strong modification of the vibrational dynamics of water in the confined state, with the disappearance of the 60 cm "1 and 170 em -1 lattice bands in the VDOS. Furthermore, the collective contribution to the polarised OH stretching band comes down indicating that the tetrabonded network is destroyed.

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