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Dynamic synthesis of a macrocycle containing a porphyrin and an electron donor

✍ Scribed by Kieran, Amy L.; Pascu, Sofia I.; Jarrosson, Thibaut; Gunter, Maxwell J.; Sanders, Jeremy K. M.

Book ID
121423000
Publisher
Royal Society of Chemistry
Year
2005
Tongue
English
Weight
136 KB
Volume
14
Category
Article
ISSN
1359-7345

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The antiaromatic macrocycle 2 has been prepared by the reaction of the bipyrrole dialdehyde 1 with hydrazine. In the crystal structure of 2β€’DMSO molecule 2 is nearly planar, the mean deviation of the 28 atoms of the core from the best least-squares plane being 0.227 Γ…. AM1 geometric optimization of