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Dynamic Processes on Solid Surfaces

✍ Scribed by Akio Yoshimori (auth.), Kenzi Tamaru (eds.)


Publisher
Springer US
Year
1993
Tongue
English
Leaves
365
Series
Fundamental and Applied Catalysis
Edition
1
Category
Library

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✦ Synopsis


When we see a jumbo jet at the airport, we sometimes wonder how such a huge, heavy plane can fly high in the sky. To the extent that we think in a static way, it is certainly not understandable. In such a manner, dynamics yields behavior quite different from statics. When we want to prepare an iron nitride, for example, one of the most orthodox ways is to put iron in a nitrogen atmosphere under pressures higher than the dissociation pressure of the iron nitride at temperatures sufficiently high to let the nitrogen penetrate into the bulk iron. This is the way thermodynamics tells us to proceed, which requires an elaborate, expensive high-pressure apparatus, sophisticated techniques, and great efforts. However, if we flow ammonia over the iron, even under low pressures, we can easily prepare the nitride-provided the hydrogen pressure is sufficiently low. Since the nitrogen desorption rate is the determining step of the ammonia decomposition on the iron surface, the virtual pressure of nitrogen at the surface can reach an extremely high level (as is generally accepted) because, in such a dynamic system, the driving force of the ammonia decomposition reaction pushes the nitrogen into the bulk iron to form the nitride. Thus, dynamics is an approach considerably different from statics.

✦ Table of Contents


Front Matter....Pages i-xv
Theory of Atomic and Electronic Structure of Surfaces....Pages 1-27
Theory of Dynamical Processes of Surfaces....Pages 29-58
Real-Time Monitoring of Surface Processes by a Novel Form of Low-Energy Ion Scattering....Pages 59-67
In Situ Observation of Surface Processes by High-Resolution UHV Electron Microscopy....Pages 69-89
Catalysis by Structurally Designed Surfaces....Pages 91-113
Surface Compounds Formed on Single-Crystal Metal Surfaces During Catalysis....Pages 115-147
Surface-Supported Metal Clusters....Pages 149-214
Laser-Induced Surface Reactions....Pages 215-235
IR Spectroscopic Studies on Surface Reactions....Pages 237-258
Catalysis by Heteropoly Compounds in the Pseudoliquid Phase....Pages 259-282
Surface Reactions Controlled by the Bulk Migration of Oxide Ions....Pages 283-305
Chirality Recognition by a Clay Surface Modified with an Optically Active Metal Chelate....Pages 307-347
Back Matter....Pages 349-357

✦ Subjects


Physical Chemistry; Organic Chemistry; Inorganic Chemistry


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