<p>When we see a jumbo jet at the airport, we sometimes wonder how such a huge, heavy plane can fly high in the sky. To the extent that we think in a static way, it is certainly not understandable. In such a manner, dynamics yields behavior quite different from statics. When we want to prepare an ir
Dynamic Chemical Processes on Solid Surfaces: Chemical Reactions and Catalysis
โ Scribed by Ken-ichi Tanaka (auth.)
- Publisher
- Springer Singapore
- Year
- 2017
- Tongue
- English
- Leaves
- 194
- Edition
- 1
- Category
- Library
No coin nor oath required. For personal study only.
โฆ Synopsis
In this book, the author determines that a surface is itself a new material for chemical reaction, and the reaction of the surface provides additional new materials on that surface. The revelation of that peculiarity is what makes this book different from an ordinary textbook, and this new point of view will help to provide a new impetus when graduate students and researchers consider their results.
The reaction of surface atoms provides additional new compounds, but these compounds cannot be detached from the surface. Some compounds are passive, but others work as catalysts. One superior feature of the surface is the dynamic cooperation of two or more different functional materials or sites on the same surface. This fact has been well established in the preferential oxidation of CO on platinum supported on a carbon nanotube with Ni-MgO at its terminal end. The Pt and Ni-MgO are perfectly separated, but these two are indispensable for the selective oxidation of CO in H2, where the H2O molecule plays a key role. The reader will understand that the complexity of catalysis is due to the complexity of the dynamic processes on the surface.
โฆ Table of Contents
Front Matter....Pages i-x
Front Matter....Pages 1-1
Introduction....Pages 3-10
Surface Structures and the Crystal Habit of Growing Particles....Pages 11-19
Self-Assembled Array of Atoms and Molecules on Metals....Pages 21-25
Formation of Quasi-Compounds on Metals....Pages 27-38
Reaction of Quasi-Compounds on Metal Surfaces....Pages 39-57
Formation of Labile Surface Compounds and Catalysis....Pages 59-73
Front Matter....Pages 75-75
Overview of Catalysis....Pages 77-83
Spatial Distribution of Molecules Desorbing with Surface Reaction....Pages 85-95
Formation of Active Ordered Layer on PtโRh Catalyst....Pages 97-114
Dynamic Chemical Processes in Catalysis....Pages 115-188
Concluding Remarks....Pages 189-192
โฆ Subjects
Catalysis;Physical Chemistry;Surfaces and Interfaces, Thin Films;Surface and Interface Science, Thin Films;Organic Chemistry;Nanochemistry
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