Dynamic NMR Investigation of the Cope Rearrangement in Solutions of Monosubstituted Bullvalenes
✍ Scribed by Poupko, R.; Zimmermann, H.; Müller, K.; Luz, Z.
- Book ID
- 126951134
- Publisher
- American Chemical Society
- Year
- 1996
- Tongue
- English
- Weight
- 329 KB
- Volume
- 118
- Category
- Article
- ISSN
- 0002-7863
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## Abstract The potential advantages of ^13^C‐(^1^H‐noise decoupled) spectroscopy (in the __Fourier__ transform mode) over ^1^H‐spectroscopy for the quantitative investigation of molecular dynamic process is discussed. The __Cope__ rearrangement in bullvalene, an example of complex exchange of spin
Homotropylidene and its bridge derivatives (e.g.bullvalene(l)) make a Cope rearrangement in a thermal process."s Recently much attention has been focused on these compounds from dynamic NMR spectroscopy 4,5 as well as synthetic and photochemical standpoints. 627 Moreover, in a theoretical field, th