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Comparison of 13C- and 1H-Magnetic Resonance Spectroscopy as Techniques for the Quantitative Investigation of Dynamic Processes. The cope rearrangement in bullvalene

✍ Scribed by Jean F. M. Oth; Klaus Müllen; Jean-Marie Gilles; Gerhard Schröder

Publisher
John Wiley and Sons
Year
1974
Tongue
German
Weight
860 KB
Volume
57
Category
Article
ISSN
0018-019X

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✦ Synopsis

Abstract

The potential advantages of ^13^C‐(^1^H‐noise decoupled) spectroscopy (in the Fourier transform mode) over ^1^H‐spectroscopy for the quantitative investigation of molecular dynamic process is discussed. The Cope rearrangement in bullvalene, an example of complex exchange of spins over different magnetic sites, has been studied by both kinds of spectroscopy as a test.

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