Dynamic Modeling of a Poly(ethylene terephthalate) Solid-State Polymerization Reactor I: Detailed Model Development
β Scribed by Algeri, Carlo; Rovaglio, Maurizio
- Book ID
- 120390130
- Publisher
- American Chemical Society
- Year
- 2004
- Tongue
- English
- Weight
- 575 KB
- Volume
- 43
- Category
- Article
- ISSN
- 0888-5885
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π SIMILAR VOLUMES
A mathematical model for solid-state polymerization of poly(ethylene terephthalate) was developed. The effects of temperature and chain entanglement on chain mobility were considered to estimate the rate constants of chemical reactions. The diffusivities of volatile byproducts could be determined us
## Abstract A comprehensive model for a semibatch ester interchange reactor has been developed with a view to investigate the effect of various process and operational variables on the DMT conversion rate as well as the byβproduct formation. The influence of important variables such as EGβtoβDMT ra