A comprehensive kinetic model for a semibatch direct esterification reactor has been developed. The solid-liquid equilibrium of terephthalic acid was considered in the modeling. Effects of the monomer feed ratio, reaction temperatures, and oligomer addition on the conversion, degree of polymerizatio
Modeling of poly(ethylene terephthalate) reactors. I. A semibatch ester interchange reactor
β Scribed by K. Ravindranath; R. A. Mashelkar
- Publisher
- John Wiley and Sons
- Year
- 1981
- Tongue
- English
- Weight
- 976 KB
- Volume
- 26
- Category
- Article
- ISSN
- 0021-8995
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β¦ Synopsis
Abstract
A comprehensive model for a semibatch ester interchange reactor has been developed with a view to investigate the effect of various process and operational variables on the DMT conversion rate as well as the byβproduct formation. The influence of important variables such as EGβtoβDMT ratio, catalyst concentration, and operational variables such as temperature and pressure has been considered. Definite conclusions concerning the choice of the desirable range of process and operational variables to maximize productivity and minimize byβproduct formation have been reached.
π SIMILAR VOLUMES
The second stage of batch poly(ethy1ene terephthalate) (PET) reactor with bis(2-hydroxyethyl) terephthalate (BHET) as the feed has been simulated. In this stage, the overall polymerization is not diffusion limited and is known to be a complex reaction. In this work it has been assumed to consist of