The dynamic electrophoretic mobility of a pair of nearby spherical particles is analyzed in the case when the thickness of the electrical double layer around each particle is comparable to the particle radius. By means of an integral reciprocal relation, a formal expression is obtained for the force
Dynamic Mobility of Colloidal Particles with Thick Double Layers
โ Scribed by Sophie E. Gibb; Robert J. Hunter
- Publisher
- Elsevier Science
- Year
- 2000
- Tongue
- English
- Weight
- 314 KB
- Volume
- 224
- Category
- Article
- ISSN
- 0021-9797
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โฆ Synopsis
The dynamic mobility spectra of several colloidal systems having a ratio of particle radius to double-layer thickness between 1 and 20 have been measured using the technique of electroacoustics. Good agreement is found between the experimental mobility spectra and the theoretical spectra generated by the computer program of Manglesdorf and White for spherical monodisperse suspensions with sizes in the neighborhood of 0.1 ยตm. Smaller and larger particles show some minor discrepancies which are more likely to be due to limitations of the model systems being used for the test than to any basic limitation of the theoretical analysis.
๐ SIMILAR VOLUMES
The dynamic mobility of a nondilute suspension of spherical particles is investigated in the case where the thickness of the electrical double layer around each particle is comparable to the particle radius. A formula is obtained for the O(ฯ) correction in a random suspension of particles with volum
Two sphere interactions were first explicitly dealt with by The electrophoretic mobilities of two interacting spheres are reflections for identical spheres (3) and for dissimilar calculated numerically for arbitrary values of the double-layer spheres (4). These calculations were checked against exac
mobility and values for the other parameters, one can extract The electrophoretic mobilities of two spherical particles are anathe average zeta potential. A comprehensive theory of this lyzed for the case where the electrical double layer is no longer kind is not at present a reality, but approximat
Dynamic mobility spectra of suspensions of semiconducting pyrolusite particles (manganese dioxide) have been measured by means of electroacoustics in different supporting electrolytes. The magnitude of the complex dynamic mobility spectra of these particles is small. At low frequency the magnitudes
Accurate approximate formulas are obtained for the dynamic electrophoretic mobility of a cylindrical hard colloidal particle in an oscillating electric field for two cases where the cylinder is in a transverse field or in a tangential field. These formulas, expressed in terms of Hankel functions and