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Dynamic analysis of efficient heme rotation in myoglobin by NMR spectroscopy

✍ Scribed by SABURONEYA, ; NORIAKIFUNASAKI, ; MIKIONAKAMURA,

Book ID
122095632
Publisher
Elsevier Science
Year
1992
Tongue
English
Weight
638 KB
Volume
1117
Category
Article
ISSN
0304-4165

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Investigation by dynamic NMR spectroscop
Investigation by dynamic NMR spectroscopy of the mechanism of rotation about the carbondouble bond in nitroenamines
✍ V. I. Bakhmutov; V. A. Burmistrov πŸ“‚ Article πŸ“… 1979 πŸ› John Wiley and Sons 🌐 English βš– 440 KB πŸ‘ 1 views

## Abstract Rapid __Z__,__E__‐isomerization of nitroenamines Rο£ΏNHο£ΏCHο£ΎC(NO~2~)COOCH~3~ in solutions was investigated by dynamic NMR spectroscopy. In weakly basic solvents all the studied nitroenamines isomerize by a thermal mechanism. In pyridine the isomerization proceeds by the thermal mechanism i