✦ LIBER ✦

DUROQUINONE AND SOME DERIVATIVES OF DURENE

✍ Scribed by Smith, Lee Irvin; Dobrovolny, F. J.

Book ID: 121017206
Publisher: American Chemical Society
Year: 1926
Tongue: English
Weight: 269 KB
Volume: 48
Category: Article
ISSN: 0002-7863
DOI: 10.1021/ja01416a043

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It has been reported previously (1) that duroquinone, in contrast to many other p-quinones (2,3), reacts with diazomethane by direct addition at the carbonyl groups. We have reinvestigated this system and find that, in fact, the reaction proceeds bJ addition to the olefinic centres of the duroquinon