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Dramatic Medium Effects on Reactivity. The Ionization Sites of Pyrrole and Indole Carboxylic Acids

✍ Scribed by Notario, R.; Abboud, J.-L. M.; Cativiela, C.; García, J. I.; Herreros, M.; Homan, H.; Mayoral, J. A.; Salvatella, L.


Book ID
127058508
Publisher
American Chemical Society
Year
1998
Tongue
English
Weight
90 KB
Volume
120
Category
Article
ISSN
0002-7863

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## Abstract The water elimination caused by bifunctional interaction in protonated dicarboxylic acids diminishes as sample pressure increases. This appears to be the result of stabilization of the protonated dixarboxylic acid by reversible formation of a protonted dimmer. The effect reaches a minim