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Medium and structural effects on the ionization constants of some pyrazole carboxylic acid derivatives

✍ Scribed by Sibel Alkan; Bülent Zeybek; Alev Doğan; Rahmi Kasımoğulları; Yunus Erdoğan; Esma Kılıç

Book ID
106214099
Publisher
Springer Vienna
Year
2008
Tongue
English
Weight
347 KB
Volume
140
Category
Article
ISSN
0026-9247

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Influence of the dielectric constant of
Influence of the dielectric constant of the medium on the dipole moment of 1/1 complexes between trialkylamines and carboxylic acids
✍ P. L. Huyskens; M. Cl. Haulait-Pirson; F. Kapuku 📂 Article 📅 2010 🏛 Wiley (John Wiley & Sons) ⚖ 361 KB 👁 2 views

## Abstract When carboxylic acids are dissolved in trialkylamines, the dipole moments μ~ab~ of the 1/1 complexes increase when the molefraction of the acid becomes greater. This is due to the enhancement of the dielectric constant of the medium which affects the transfer constant K~t~ of the proton