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Dramatic Ligand Effects on Gas-Phase Transition-Metal Reactivity and Selectivity: Studies of Fe + , Fe + (H 2 O), and Fe + (CO) with Propane

✍ Scribed by Armentrout, P. B.; Tjelta, Brenda L.


Book ID
125513879
Publisher
American Chemical Society
Year
1997
Tongue
English
Weight
80 KB
Volume
16
Category
Article
ISSN
0276-7333

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MΓΆssbauer study of the phase transitions
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The Miissbauer spectra of iron and cobalt fluoroborate hexahydrate show a change by a factor of two in the quadrupole interaction near 2%) K and 185 K, respectively, togtther with a sudden drop in resonance fraction. This behaviour is explained as a first order phase transition in which the axial pa