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Double nucleophilic addition of carbon donors to [(benzene)(arene)Ru]2+ cations

โœ Scribed by Neto, Catherine Camaioni; Sweigart, Dwight A.


Book ID
121235371
Publisher
The Royal Society of Chemistry
Year
1990
Tongue
English
Weight
226 KB
Volume
23
Category
Article
ISSN
0022-4936

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โœ Anthony J. Pearson; Manoj Babu ๐Ÿ“‚ Article ๐Ÿ“… 1998 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 215 KB

Addition of carbon nucleophiles, such as phenylmagnesium bromide, to isoprene-Mo(CO)2Tp (Tp = hydridotris(l-pyrazolyl)borato), can proceed with excellent regiocontrol, predominantly at the diene terminus remote from the 2-methyl substituent. In contrast to the corresponding cyclopentadienyl complex,