Double layer studies of aqueous sodium citrate solution at the mercury electrode
β Scribed by R.G. Barradas; G.J. Donaldson; D.W. Shoesmith
- Book ID
- 104149600
- Publisher
- Elsevier Science
- Year
- 1973
- Weight
- 813 KB
- Volume
- 41
- Category
- Article
- ISSN
- 0022-0728
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π SIMILAR VOLUMES
Differential-capacitance/potential curves were measured at the interface between mercury and dilute aqueous solutions of HClO,, NaClO,, NaOH, CH,COOH and NH,OH. In the potential region near the zero-charge potential, the double-layer behaviour of these systems is in agreement with Grahame's theory.
The adsorption of CFSCOO ions at the H&aqueous CF,COOH interphase was studied, using both differential and electrocapillary measurements. The hump of the C,-E curve diminishes as the concentration increases from the 0.2 M solution, which is attributed to adsorption of undissociated CF,COOH molecules